Process for preparation of Mannich reaction products from oxidized polymers

ABSTRACT

A process for the preparation of oil-soluble Mannich condensation products wherein an amine is prereacted with a sulfonic acid or ammonium sulfonate, oleic acid, and an oxidized olefin polymer and the prereaction product is reacted with an aldehyde.

FIELD OF THIS INVENTION

The field of this invention relates to lubricating oil compositions. More particularly, this invention relates to a lubricating oil composition containing an improved dispersant-viscosity index improver and to the process for preparing the improved dispersant-viscosity index improver. Even more particularly, this invention relates to a process for preparing oil-soluble Mannich condensation products from oxidized olefin polymers, amines and aldehydes wherein the amine is prereacted with a sulfonic acid or ammonium sulfonate in the presence of said oxidized olefin polymers and oleic acid wherein the mole ratio of oleic acid to amine is in the range of from about 0.025 to about 10.0, preferably from about 0.05 to about 1.0, and the prereaction product is reacted with an aldehyde to form the Mannich condensation product.

DESCRIPTION OF THE PRIOR ART

Lubricant deterioration caused by the operation of diesel and spark ignition internal combustion engines results in the formation of sludge, lacquer and resinous deposits on interior surfaces of the engines. This foreign matter accelerates wear and reduces engine efficiency. In order to prevent or reduce the formation of these deposits, a wide variety of lubricating oil additives have been developed which have dispersancy and detergency properties. These additives have the ability to keep deposit-forming materials suspended in the oil so that the engine remains in a clean and efficient operating condition.

It is well known that lubricating oils become thin at elevated temperatures while thickening at low temperatures. Generally certain additives improve lubricant oil temperature viscosity relationships. In the case of crankcase lubricants, the oil must not become so thick when cold that the engine is prevented from operation. At the same time, when the engine has heated up in operation, the oil must remain sufficiently viscous to maintain oil films for lubrication of moving parts. Various additives provide both detergent and viscosity index improvement to lubricants.

Culbertson et al., U.S. Pat. No. 3,872,019, issued Mar. 18, 1975, discloses and claims bifunctional lubricant additives exhibiting both dispersant and viscosity index improving properties obtained by the Mannich condensation of an oxidized long chain, high molecular weight amorphous copolymer of essentially ethylene and proylene having a number average molecular weight of at least about 10,000 and at least 140 pendant methyl groups per 1,000 chain carbon atoms with a formaldehyde yielding reactant and a primary or secondary amine or polyamine, said reactants being employed in the molar ratio of from about 1:2:2 to about 1:20:20, respectively.

West, U.S. Pat. No. 4,131,553, issued Dec. 26, 1978, incorporated herein by reference, discloses and claims a process for preparing a dispersant-viscosity index improver comprising products of the Mannich condensation reaction of oxidized olefinic polymers. The Mannich reaction is carried out in the presence of an oil soluble sulfonic acid. The sulfonic acid catalyzes the reaction, increases the resistance of the Mannich modified oxidized polymer to oxidation and varnish formation, increases the detergent-dispersing properties of the viscosity index improver, does not appreciably harm the color of the product and increases the performance of the additive in engine tests.

Schaffhauser et al., U.S. Pat. No. 4,444,956, issued Apr. 24, 1984, incorporated herein by reference, teaches and claims a process for the preparation of oil-soluble Mannich condensation products wherein an amine is reacted with a sulfur-containing compound selected from the group consisting of oil-soluble sulfonic acids and their ammonium salts, and reacting the product thereof with formaldehyde and an oxidized polymer derived from an amorphous olefin polymer.

It has been found that dispersant viscosity index improvers prepared as Mannich condensation products upon storage at elevated temperatures develop a haze condition wherein clarity of the product is significantly decreased to a degree wherein marketability and customer acceptance of the product is affected.

Accordingly, it is an object of this invention to provide a new process for the preparation of oil-soluble Mannich condensation products.

Another object of this invention is to provide an improved process for the preparation of oil-soluble Mannich condensation products.

A still further object of this invention is to provide an oil-soluble Mannich condensation product having reduced haze and sediment.

SUMMARY OF THE INVENTION

The present invention is directed to the discovery of an improved process for the preparation of oil-soluble Mannich condensation products which involves the reaction of an aldehyde with an amine and oxidized olefin polymer which have been prereacted with a sulfonic acid or ammonium sulfonate and oleic acid. The oil-soluble Mannich condensation products prepared thereby have reduced haze and sediment.

DETAILS OF THE INVENTION

We have found that oil-soluble Mannich condensation products prepared in accordance with this invention possess excellent dispersancy and viscosity improving properties when incorporated into lubricating oils. In addition, the Mannich products of this invention also possess improved filterability and reduced haze or sediment in comparison with prior art products. In particular, the subject invention is an improvement in the process which is disclosed by the above-mentioned U.S. Pat. No. 4,444,956 to Schaffhauser et al., which, in turn, is an improvement in the process which is disclosed in the above mentioned U.S. Pat. No. 4,131,553 to West. These patents are hereby incorporated in their entirety by reference.

As used herein, the terminology "amorphous olefin polymer" refers to amorphous addition polymers derived from olefinically unsaturated hydrocarbon monomers or mixtures thereof. Such olefin monomers include olefins of the formula R--CH═CH₂ wherein R is selected from the group consisting of hydrogen and aliphatic groups of from 1 to about 20 carbon atoms. Suitable olefin monomers include, but are not limited to, ethylene, propylene, isobutylene, 1-butene, 1-hexene, and 4-methyl-1-pentene. Olefin monomers having a plurality of double bonds and containing from 4 to about 25 carbon atoms can also be used. Suitable monomers containing a plurality of double bonds include, for example, 1,3-butadiene, 1,4-hexadiene, 1,4-pentadiene, 2-methyl-1,5-hexadiene, 1,7-octadiene, 5-methylene-2-norbornene and norbornadiene.

Preferred amorphous olefin polymers are derived from about 30 to about 80 mole percent ethylene and from about 20 to about 70 mole percent of at least one comonomer selected from the group consisting of olefins of the formula R--CH═CH₂ wherein R is an aliphatic group of from 1 to about 20 carbon atoms and diolefins of from 4 to about 25 carbon atoms.

Highly preferred amorphous olefin polymers include ethylene-propylene copolymers which are derived from about 35 to about 80 and preferably from about 55 to about 65 mole percent of ethylene, and from about 20 to about 65 and preferably from about 35 to about 45 mole percent of propylene. These ethylene-propylene copolymers have a number average molecular weight in the range of from about 5,000 to about 200,000, preferably from about 20,000 to about 70,000, and contain at least 100 pendant methyl groups per 1,000 chain carbon atoms.

Methods for the preparation of the amorphous olefin polymers are well known. For example, methods for the preparation of such polymers are described in U.S. Pat. Nos. 2,700,633; 2,726,231; 2,933,480; 3,000,866; 3,063,973; 3,093,621; and 3,872,019.

The amorphous olefin polymer must be oxidized prior to use in the process of this invention. The oxidation can be accomplished by contacting the polymer at a suitable temperature and pressure with an oxidizing agent such as air, free oxygen or any oxygen-containing material which is capable of releasing oxygen under the oxidation conditions selected. If desired, the oxidation can be conducted in the presence of known oxidation catalysts, such as platinum or a platinum group metal and compounds containing metals such as copper, iron, cobalt, cadmium, manganese, and vanadium. The oxidation can be carried out, for example, by the methods which are described in U.S. Pat. Nos. 2,982,728; 3,153,025; 3,316,177; 3,365,499; 3,544,520 and 4,011,380. The aforementioned U.S. Pat. No. 4,011,380 to West et al. is hereby incorporated in its entirety by reference.

Depending on the activity of the specific oxidizing agent and the rate of reaction desired, the oxidation of the olefin polymer can be carried out over a wide temperature range. With an active oxidizing agent such as sulfur trioxide, temperatures in the range of from about -40° to about 200° C. can be used. On the other hand, with less active oxidizing agents such as air, temperatures in the range of from about 40° to about 430° C. can be used. The amorphous olefin polymer is desirably dissolved in oil prior to the oxidation in order to provide a reaction mixture of convenient viscosity. Reaction parameters such as temperature, pressure, oxidizing agent, concentration of oxidizing agent, and oxidation catalyst, if any, are selected and controlled in a conventional manner to obtain optimum results.

The oxidized olefin polymer for use in the process of this invention desirably has a number average molecular weight of at least about 3,000, preferably from about 10,000 to about 100,000, and more preferably from about 10,000 to about 50,000. In addition, the ratio of the weight average to the number average molecular weight (M_(w) /M_(n)) of the oxidized polymer is desirably less than about 6 and preferably less than about 3. Although the invention is not to be so limited, the oxidized olefin polymer is believed to comprise a degradation product of lower molecular weight than the amorphous olefin polymer starting material which contains ketone carbonyl groups.

Suitable aldehydes for use in the practice of this invention include low molecular weight aliphatic aldehydes of from 1 to about 5 carbon atoms. Such aldehydes include, for example, formaldehyde, acetaldehyde, propionaldehyde and n-butyraldehyde. However, the use of formaldehyde or a formaldehyde-yielding reagent, such as formalin and paraformaldehyde, is highly preferred.

Amines which are suitable for use in the process of this invention include amines which are selected from the group consisting of primary and secondary aliphatic amines having from 1 to about 24 carbon atoms, aliphatic diamines of the formula H₂ N(CH₂)_(x) NH₂ wherein x is an integer from 3 to about 10, and polyamines of the formula H₂ N(A--NH)_(y) H wherein A is a divalent alkylene radical of from 2 to about 6 carbon atoms and y is an integer from 1 to about 10. Suitable primary and secondary aliphatic amines are those of the formula R¹ R² NH wherein R¹ is selected from the group consisting of hydrogen and aliphatic groups containing from 1 to about 12 carbon atoms and R² is selected from the group consisting of aliphatic groups containing from 1 to about 12 carbon atoms. The group of amines which is suitable for use in this invention includes, but is not limited to, methylamine, dibutylamine, cyclohexylamine, propylamine, decylamine, ethylenediamine, 1,3-diaminopropane, 1,4-diaminopropane, 1,6-diaminohexane, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, tripropylenetetramine and tetrapropylenepentamine.

The oil-soluble sulfonic acids which are suitable for use in the practice of this invention are desirably hydrocarbyl sulfonic acids which have an equivalent weight in the range of from about 250 to about 2,000, and preferably from about 400 to about 1,000. In more detail, these sulfonic acids can be represented by formulas I and II:

    (R.sup.1).sub.x --Ar--(SO.sub.3 H).sub.y                   I

    R.sup.2 --(SO.sub.3 H).sub.z                               II

In formula I, Ar is a cyclic organic nucleus of the mono- or polynuclear type, including benzenoid or heterocyclic nuclei such as that of benzene, naphthalene, anthracene, 1,2,3,4-tetrahydronaphthalene, thianthrene or biphenyl and the like. Preferably, however, Ar is an aromatic hydrocarbon nucleus, especially a benzene or naphthalene nucleus. R¹ is an aliphatic or substituted aliphatic group, examples of which include alkyl, alkenyl, alkoxy, alkoxyalkyl, carboalkoxyalkyl and aralkyl groups. Both x and y are independently an integer which is at least 1, with the proviso that the variables represented by (R¹)_(x) are such that the acid is oil-soluble. This means that the groups represented by (R¹)_(x) should provide at least about eight aliphatic carbon atoms per molecule of sulfonic acid, and preferably at least about twelve aliphatic carbon atoms. Preferably, x and y are integers of from 1 to 3. Finally, the R¹ and Ar groups in formula I can carry substituents such as hydroxy, mercapto, halogen, amino, carboxy, lower carboalkoxy and the like so long as the essentially hydrocarbon character of the groups is not destroyed.

In formula II, R² is an aliphatic or substituted aliphatic group which desirably contains a total of at least about 12 carbon atoms. Examples of suitable R² groups include alkyl, alkenyl, and alkoxyalkyl groups and also substituted alicyclic groups wherein the substituents are alkoxy, alkoxyalkyl, and carboalkoxyalkyl. Generally, the alicyclic group is a cycloalkane nucleus such as cyclopentane, cyclohexane, cyclohexene, and the like. Specific examples of R² include cetylcyclohexyl, laurylcyclohexyl, ethoxycetyl and octadecenyl as well as groups derived from paraffin waxes and polyolefins, including polymerized mono- and diolefins containing from about 1 to 8 carbon atoms per olefin monomer unit. The R² group in formula II can carry substituents such as hydroxy, mercapto, halogen, amino, carboxy, carboalkoxy and the like so long as the essentially hydrocarbon character of the group is not destroyed. Finally, z in formula II is an integer of from 1 to 3.

Illustrative examples of suitable sulfonic acids include mahogany sulfonic acids, petrolatum sulfonic acids, mono- and polywax-substituted naphthalene sulfonic acids, polyolefin-substituted benzene sulfonic acids, dilaurylbenzene sulfonic acids, laurylcetylbenzene sulfonic acids, cetylchlorobenzene sulfonic acids, cetylphenol sulfonic acids, cetylphenol disulfide sulfonic acids, dilauryl-beta-naphthol sulfonic acids, paraffin wax sulfonic acids, petroleum naphthene sulfonic acids, laurylcyclohexyl sulfonic acids, mono- and polywax-substituted cyclohexyl sulfonic acids and the like.

Suitable polyolefin-substituted benzene sulfonic acids for use in this invention include polypropylenealkylated benzene sulfonic acids and polybutylenealkylated benzene sulfonic acids wherein the polypropylene and polybutylene substituents have a molecular weight of at least about 100, desirably within the range of about 100 to about 1,900, and preferably from about 250 to about 850. Other suitable oil-soluble sulfonic acids are well described in the art including, for example, U.S. Pat. Nos. 2,616,604; 2,626,207; and 2,767,209.

Aromatic sulfonic acids of the type set forth in formula I are generally preferred over the aliphatic sulfonic acids of formula II in view of their ready availability and somewhat greater thermal stability at elevated temperatures.

Ammonium sulfonates which are suitable for use in the practice of this invention are derived from the above-described oil-soluble sulfonic acids. These ammonium salts can be obtained, for example, by neutralization of the sulfonic acids with ammonia gas or with ammonium hydroxide. It will be appreciated that the sulfonic acid can be at any convenient temperature and in a suitable solvent or neat during the neutralization.

In the practice of this invention, the amine is prereacted with sulfonic acid or its ammonium salt in the presence of the oxidized olefin polymer and oleic acid before reaction with the aldehyde. The ratio of equivalents of sulfonic acid or its ammonium salt to equivalents of amine used in the preparation of this prereaction product is desirably from about 0.05 to about 10 and preferably from about 0.1 to about 1. The ratio of equivalents of oleic acid to equivalents of amine is desirably from about 0.025 to about 10 and preferably from about 0.05 to about 1.0. Although any suitable reaction temperature can be used, the reaction temperature is desirably between about 0° and about 250° C., and preferably between about 10° and about 200° C. The prereaction product can be prepared in the presence of a nonreactive solvent or diluent, if desired. In particular, the amine is preferably substantially anhydrous. If desired, the prereaction product can be prepared and stored for substantial periods of time prior to use.

Alternatively, prereaction product of the amine with sulfonic acid of its ammonium salt and oleic acid is condensed in a separate step before reaction with the oxidized olefin polymer and aldehyde. The mole ratio of oxidized olefin polymer to aldehyde to amine in the prereaction product is desirably in the range from about 1:2:2 to about 1:500:500 (based on the number average molecular weight of the oxidized olefin polymer and either the amount of aldehyde or the potential amount of aldehyde represented by an aldehyde-yielding reagent) and preferably from about 1:25:25 to about 1:500:500. Although any suitable reaction temperature can be used for this alternative procedure, the reaction temperature is desirably between about 0° and about 300° C. and preferably between about 50° and about 250° C. Although not necessary, the condensation is desirably conducted in the presence of a solvent or diluent, for example, an aromatic hydrocarbon solvent such as benzene, toluene, and xylene or an aliphatic hydrocarbon solvent such as hexane. A low viscosity hydrocarbon oil such as a solvent-extracted SAE 5W mineral oil is particularly suitable as a solvent or diluent. The use of a solvent is advantageous to facilitate the mixing of the reactants and for control of the reaction temperature.

If desired, the precondensation of the amine with sulfonic acid and/or ammonium sulfonate, oleic acid, and oxidized olefin polymer and the second step condensation reaction between the precondensation product and aldehyde can be carried out under an inert atmosphere, such as nitrogen, in order to prevent any possible oxidative degradation by air.

The Mannich reaction product has a viscosity increase of from about 100 to 2,000 Saybolt Universal Seconds (SUS) at 100° C., depending upon the mole ratio of the oxidized copolymer to mole ratio of the amine. The viscosity increase is defined as the increase in viscosity over the viscosity of the oxidized copolymer as reacted with said amine.

Although the process of this invention is not to be so limited, it is believed to represent a variation of the Mannich reaction. That is to say, it is believed that the process of this invention involves the replacement of active hydrogen atoms in the oxidized olefin polymer by substituted aminomethyl groups. The subject process results in the formation of a nitrogen-containing product which possesses dispersant properties and is also an excellent viscosity index improver.

The chemical composition of the product obtained by the process of this invention cannot be characterized by a precise structural formula. While it is believed that the oxidation of the olefin polymer produces large amounts of ketones, it is known that minor amounts of aldehydes, acids and perhaps esters may also be present. In view of the complex chemical character of the oxidized olefin polymer, this material must be defined by its method of preparation. Since such an oxidized olefin polymer is a starting material for the process of this invention, the resulting product must also be defined by its method of preparation.

The Mannich product prepared in accordance with the process of this invention can be incorporated into a lubricating oil by simple mixing. Suitable lubricating oils include, for example, mineral oils; synthetic materials such as olefin polymers, polyoxypropylene and certain dicarboxylic acid esters; vegetable oils such as cottonseed oil, corn oil and castor oil; and animal oils such as lard oil and sperm oil. A lubricating oil composition will typically comprise a major portion of a lubricating oil in combination with the Mannich product, wherein the amount of Mannich product is from about 0.01 to about 5 weight percent of the lubricating oil composition.

Concentrates containing from about 5 to about 75 weight percent or more of the subject Mannich product in a suitable base oil, either alone or in combination with other well-known lubricant additives, can be used for blending with lubricating oils in the proportions desired for particular conditions or used to give a finished product containing from about 0.01 to about 5 weight percent of the Mannich product.

The Mannich product of this invention can be used in combination with other conventional lubricating oil additives which include, but are not limited to, wear inhibitors, extreme pressure agents, friction modifiers, antioxidants, corrosion inhibitors, detergents, dispersants, antifoam agents, viscosity index improvers and pour point depressants.

The following examples are intended only to illustrate the invention and are not to be construed as imposing limitations on it.

EXAMPLE I

A 100-gram portion (0.13 equivalent) of the ammonium salt of a polypropylene-substituted benzene sulfonic acid having a molecular weight of 782 was heated with stirring to 104° C. under nitrogen, and 60.3 grams (0.52 equivalent) of hexamethylenediamine (98% pure, mp 40°-42° C.) which had been heated to the liquid state was added in portions over a period of about 10 minutes. After completion of the hexamethylenediamine addition, stirring was continued for one hour. The resulting product was stable for at least one month.

EXAMPLE II

To 319.8 grams (0.41 equivalent) of the ammonium sulfonate described in Example I were added, at room temperature with stirring and under nitrogen, 200 grams (1.69 equivalents) of hexamethylenediamine (98% pure, mp 40°-42° C.) which had been warmed to the liquid state. The temperature of the reaction mixture rose from 28° to 38° C. during the addition period and an evolution of ammonia resulted in foaming during the initial stages of the reaction. The foaming was controlled by addition of a trace of a polymethylsiloxane antifoaming agent.

EXAMPLE III

To 319.8 grams (0.41 equivalent) of the ammonium sulfonate described in Example I were added, at rooom temperature with stirring and under nitrogen, 285 grams (1.72 equivalents) of a 70% aqueous solution of hexamethylenediamine. Heavy foaming was observed during the first one-third of the addition. The resulting product was low in viscosity, homogeneous at room temperature and analyzed for 8.07% nitrogen.

EXAMPLE IV

A 7.0% solution of an amorphous ethylene-propylene copolymer (containing about 60 mole percent ethylene and having a number average molecular weight of about 60,000) in a 100 neutral mineral oil, which also contained about 0.2 weight percent of an overbased magnesium alkylbenzene sulfonic acid and about 0.2 weight percent of an alkylbenzene sulfonic acid, was treated with a 50/50 mixture of air and nitrogen with stirring at a temperature of about 180° C. until oxidative degradation of the polymer reduced the viscosity of the mixture to about 4,000 Saybolt Universal Seconds at 99° C. To 4,000 parts of this oxidized polymer solution at 182° C. and under a nitrogen atmosphere were added, in one portion, 132 parts of the product of Example II. After 15 minutes, 68.6 parts of a 37.5% formaldehyde solution were added over a 45-minute period. The resulting mixture was stirred for two hours at 182° C. with a stream of nitrogen which was introduced at the bottom of the reaction vessel. The resulting product contained 1,310 ppm of nitrogen and could be clarified by filtration through a combination of filter paper and a one-inch bed of 535 Celite at a temperature of about 120° C.

EXAMPLE V

Example IV was repeated except that the amount of the product of Example II and the amount of formaldehyde solution were reduced to 88 parts and 46 parts, respectively, to give a product containing 828 ppm of nitrogen.

EXAMPLE VI

Example IV was repeated except that the amount of the product of Example II and the amount of formaldehyde solution were reduced to 66 parts and 34.3 parts, respectively, to give a product containing 572 ppm of nitrogen.

EXAMPLE VII

Example IV was repeated except that 100 parts of the product of Example III were used in place of the product of Example II and the amount of formaldehyde solution was reduced to 46 parts to give a product containing 1,000 ppm of nitrogen. Addition of the product of Example III to the oxidized polymer solution required 12 minutes as a consequence of foaming as water distilled off.

EXAMPLE VIII

Example IV was repeated except that 52 parts of hexamethylenediamine and 82 parts of the ammonium sulfonate described in Example I were individually added to the oxidized polymer in place of the product of Example II. The resulting product contained 989 ppm of nitrogen.

EXAMPLE IX

Example VI was repeated except that 26 parts of hexamethylenediamine and 41 parts of the ammonium sulfonate described in Example I were individually added to the oxidized polymer in place of the product of Example II. The resulting product contained 733 ppm of nitrogen.

EXAMPLE X

The spot dispersancy test gives a measure of the ability of a dispersant to disperse sludge and varnish when incorporated into a lubricating oil. In this test, a measured amount of the dispersant is mixed with a measured amount of crankcase lubricant oil which has been used in a Ford Sequence VC Engine Test for 192 hours. The mixture is heated with stirring at 300° F. (149° C.) for 16 hours. An aliquot of the resulting material is then spotted on a standard white blotter paper. Since dispersancy is reflected by the ability of the lubricant composition to keep sludge in suspension, dispersancy will also be reflected by the ratio of the diameters of the sludge and oil rings formed on the blotter paper. A spot dispersancy rating is obtained by dividing the diameter of the sludge ring by the diameter of the oil ring and multiplying by 100. A high numerical rating indicates good dispersancy.

The spot dispersancy ratings of the products of Examples IV-X are set forth in Table I. In addition, the haze before filtration of the products of Examples IV-X diluted with 85 vol.% naphtha is also set forth in Table I using a scale ranging from A to E, with A representing a crystal clear material which is free of haze and E representing an extremely hazy material which is virtually opaque.

                  TABLE I                                                          ______________________________________                                                           Nitrogen           Spot                                                        Concen-    Haze    Disper-                                           Product   tration,   Before  sancy                                     Entry   of Example                                                                               ppm        Filtration.sup.a                                                                       Rating.sup.b                              ______________________________________                                         1       IV        1310       B       91                                        2       V         828        B       89                                        3       VI        572        A       89                                        4       VII       1000       C       83                                        5       VIII      989        E       91                                        6       IX        756        B       76                                        ______________________________________                                          .sup.a Sample diluted with 85 vol. % naphtha.                                  .sup.b Carried out using a lubricant composition containing 15% of the         test material.                                                           

EXAMPLE XI

A 7.0% solution of an amorphous ethylene-propylene copolymer of Example IV was treated until the viscosity of polymer mixture was reduced to 1,700 Saybolt Universal Seconds at 100° C. To 5,000 parts of this oxidized polymer solution at 150° C., were added 17 parts of hexamethylene diamine and 17 parts of the ammonium salt of a polypropylene-substituted benzene sulfonic acid having a molecular weight of 650 under good stirring. After 15 minutes, 30 parts of 37% formaldehyde solution were added over a 30 minute period. The resulting product has increased viscosity of 2,150 Saybolt Universal Seconds at 100° C. and contained 717 ppm of nitrogen.

EXAMPLE XII

Example XI was repeated except that 24.5 parts of 70% aqueous hexamethylene was addded.

EXAMPLE XIII

Example XI was repeated except that the amount of the ammonium salt was increased to 34 l parts.

EXAMPLE XIV

Example XII was repeated except that 1.84 parts of oleic acid (282 equivalent weight) was added after hexamethylene diamine addition.

EXAMPLE XV

Commercial size batches of the products of Examples XII and XIV were prepared and tested for product neat haze (undiluted product) in an Amoco hazeometer. Results are in Table II. Products prepared according to the procedure of Example XII were considered as controls. Products prepared according to the procedure of Example XIV were designated "Oleic".

                  TABLE II                                                         ______________________________________                                                       Batch No.                                                                              Haze                                                     ______________________________________                                         Control          8 to 13  B-C                                                                  14 to 19  G-H                                                  Oleic           --        A                                                    Control         62 to 63  I                                                    Oleic           64        C                                                    Control         66 to 67  H                                                    Oleic           65        C-D                                                  ______________________________________                                    

The results in Table II demonstrate that the prereaction of the amine with the ammonium sulfonate and oleic acid affords a product having a substantially reduced haze prior to filtration. The reduction in haze and sediment which is provided by the process of this invention is such that filtration is simplified and may be unnecessary. 

What is claimed is:
 1. A process for the preparation of an oil-soluble condensation product which comprises:(a) reacting at least one amine selected from the group consisting of primary and secondary aliphatic amines having from 1 to about 24 carbon atoms, aliphatic diamines of the formula H₂ N(CH₂)_(x) NH₂ wherein x is an integer from 3 to about 10, and polyamines of the formula H₂ N(A--NH)_(y) H wherein A is a divalent alkylene radical of from 2 to about 6 carbon atoms and y is an integer from 1 to about 10, with at least one sulfur-containing material selected from the group consisting of oil-soluble sulfonic acids and their ammonium salts, and oleic acid wherein the ratio of mole equivalents of said sulfur-containing material to mole equivalents of said amine is from about 0.05 to about 10; and ratio of mole equivalents of said oleic acid to equivalents of said amine is from about 0.025 to about 10; and an oxidized polymer wherein said oxidized polymer is derived from an amorphous olefin polymer and has a number average molecular weight of at least about 3,000 and (b) reacting the product of (a) with formaldehyde or a formaldehyde-yielding reagent (c) recovering the oil-soluble condensation product which has a viscosity increase of from 100 to 2,000 Saybolt Universal Seconds at 100° C. over the viscosity of said oxidized copolymer.
 2. The process as set forth in claim 1 wherein said sulfur-containing material is selected from the group consisting of polyolefin-substituted benzene sulfonic acids having an equivalent weight in the range from about 250 to about 2,000 and their ammonium salts.
 3. The process as set forth in claim 2 wherein said sulfur-containing material is selected from the group consisting of polypropylene-substituted benzene sulfonic acids having an equivalent weight in the range from about 400 to about 1,000 and their ammonium salts.
 4. The process as set forth in claim 1 wherein said oxidized polymer is an oxidation product of a polymer which is derived from about 30 to about 80 mole percent ethylene and from about 20 to about 70 mole percent of at least one comonomer selected from the group consisting of olefins of the formula R--CH═CH₂ wherein R is an aliphatic group of from 1 to about 20 carbon atoms and diolefins of from 4 to about 25 carbon atoms.
 5. The process as set forth in claim 4 wherein said oxidized polymer is an oxidation product of a polymer which is a copolymer of ethylene and propylene having an ethylene content of about 35 to about 80 mole percent and a propylene content of from about 20 to about 65 mole percent.
 6. The process as set forth in claim 5 wherein said copolymer has an ethylene content of about 55 to about 65 mole percent and a propylene content of about 35 to about 45 mole percent.
 7. The process as set forth in claim 6 wherein said formaldehyde-yielding reagent is selected from the group consisting of formalin and paraformaldehyde.
 8. The process as set forth in claim 7 wherein said amine is hexamethylenediamine.
 9. The process as set forth in claim 1 wherein said amine and said sulfur-containing material are reacted at a temperature in the range from about 0° to about 250° C.
 10. The process as set forth in claim 1 wherein said reaction of the product of (a) with formaldehyde or a formaldehyde-yielding reagent is carried out at a temperature in the range from about 0° to about 300° C.
 11. The process as set forth in claim 1 wherein said amine is substantially anhydrous.
 12. The process as set forth in claim 1 wherein the ratio of oxidized polymer to formaldehyde or formaldehyde-yielding reagent to amine is in the range from about 1:25:25 to about 1:500:500, wherein said ratio is based on the number average molecular weight of the oxidized polymer and either the amount of formaldehyde or the potential amount of formaldehyde represented by said formaldehyde-yielding reagent.
 13. The oil-soluble condensation product prepared by the process of claim
 1. 